Physical Chemistry Seminar, Dr. Sanat Kumar, Columbia University

October 11, 2018 - 01:00 PM - 02:00 PM

Dr. Sanat Kumar

"Polymer-Grafted Nanoparticle Membranes with Controllable Free-Volume"


-Polymer based membranes play a key role in several industrially important gas separation technologies, e.g., removing CO2 from natural gas, with enormous economic and environmental impact. Baker advocates the development of novel membrane architectures since current, pure polymer membranes only offer limited systematic pathways for improvement. Here, we develop a novel hybrid membrane construct comprised entirely of nanoparticles grafted with polymers. These membranes are shown to have broadly tunable separation performance through variations in graft density and chain length. Computer simulations show that the optimal NP packing forces the grafted polymer layer to distort, yielding regions of measurably lower polymer density. Multiple experimental probes confirm that these materials have the predicted increase in “polymer free volume”, which explains their improved separation performance. These polymer-grafted NP materials thus represent a new template for rationally designing membranes with desirable separation abilities, coupled with improved aging characteristics in the glassy state and enhanced mechanical behavior.
Carol Lynch Lecture Hall Chemistry Complex

Host: Dr. Fakhraai




Department of Chemistry

231 S. 34 Street, Philadelphia, PA 19104-6323

215.898.8317 voice | 215.573.2112 fax |