Inorganic

Inorganic Chemistry Seminar: Dr. Brad P. Carrow, Princeton

Tue, 2019-02-05 12:00 - 13:00
Speaker: 

Brad P. Carrow

Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr. Schelter

title and abstract :TBA

inquires rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr. David Goldberg, Johns Hopkins University

Tue, 2019-02-26 12:00 - 13:00
Speaker: 
Dr. David Goldberg
Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Tomson

Title & Abstract TBA

inquires rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr. Amy Prieto, Colorado State University

Tue, 2018-10-16 12:00 - 13:00
Speaker: 

Dr. Amy Prieto

Title "Inexpensive, Efficient Approaches for Energy Production and Storage"

 

 We are interested in developing new synthetic methods for nanoscale materials with applications in energy conversion and storage. For this talk, I will focus first on using photovoltaic devices to produce energy, and in particular the synthesis and characterization of Cu2ZnSnS4 nanoparticles. The structure-property relationships for these particles can be significantly modified as the metal and chalcogen stoichiometries are tuned.  Second, I’ll discuss our efforts to develop new architectures for rechargeable Li-ion batteries for storing that energy. We are working to incorporate high surface area structures of a novel anode material into a new battery architecture wherein the current collector is conformally coated with an electrolyte made by electrochemical deposition, then surrounded by the cathode electrode. The significant advantage is that the diffusion length for Li+ between the cathode and anode will be dramatically reduced, which should lead to much faster charging rates. The general theme between both topics is the development of new synthetic methods for useful materials with an eye toward non-toxic, earth abundant chemicals and reasonable manufacturing methods.

 

 

M. C. Schulze, R. K. Schulze, A. L. Prieto "Electrodeposited thin-film CuxSb anodes for Li-ion batteries: Enhancement of cycle life via tuning of film composition and engineering of the film-substrate interface" J. Mater. Chem. A20186, 12708-12717.


 

M. Braun, L. Korala, J.  M. Kephart, and A. L. Prieto, “Synthetic Control of Quinary Nanocrystals of a Photovoltaic Material: The Clear Role of Chalcogen Ratio on Light Absorption and Charge Transport for Cu2ZnSn(S1-xSex)4”, ACS Appl. Energy Mater.2018 1(3), 1053-1059.


 

Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr Goldberg

inquires rvargas@sas.upenn.edu

Inorganic Chemistry Seminar, Dr. Hemamala Karunadasa, Stanford University

Tue, 2018-09-04 12:00 - 13:00
Speaker: 

Dr. Hemamala Karunadasa

Title

Between the sheets: The molecular chemistry of hybrid perovskites

Abstract

The tools of synthetic chemistry allow us to tune molecules with a level of precision not yet accessible with inorganic solids. We have investigated hybrid perovskites that couple organic small molecules with the optical and electronic diversity of extended inorganic solids. I will share our current understanding of these materials, whose technologically relevant properties are highly amenable to synthetic design.

The 3D lead-iodide perovskites have recently been identified as low-cost absorbers for high-efficiency solar cells. Although the efficiencies of devices with perovskite absorbers have risen at an impressive rate, the materials’ intrinsic instability and toxicity may impede their commercialization. I will discuss methods developed by our group to address these problems. The 2D hybrid perovskites have dramatically different properties from their 3D congeners. We discovered that some 2D perovskites emit broadband white light (similar to sunlight) when excited by UV light. I will discuss how these materials, which do not contain extrinsic dopants or obvious emissive sites, could emit every color of visible light. Although the organic molecules in hybrid perovskites have mostly played a templating role, we have investigated their role in engendering reactivity. I will describe reactions that occur between the inorganic sheets, which allow these nonporous solids to capture small molecules.

Brief Bio

Hema Karunadasa studied solid-state chemistry with Bob Cava at Princeton University and molecular catalysis with Jeff Long and Chris Chang at UC Berkeley and with Harry Gray at the California Institute of Technology. She joined Stanford Chemistry as an assistant professor in 2012. Her group synthesizes hybrid materials that harness the advantages of extended solids and discrete molecules.

Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Attached Document: 

Host: Dr. Murray

inquiries rvargas@sas.upenn.edu

Inorganic Chemsitry Seminar: Dr. Matthew Kieber-Emmons, University of Utah

Tue, 2019-04-23 12:00 - 13:00
Speaker: 
Dr. Matthew Kieber-Emmons
Location: 

Carol Lynch Lecture Hall

Chemsitry Complex

Host: Tomson

Title & Abstract: TBA

inquiries rvargas@sas.upenn.edu

Inorganic Chemistry Seminar; Dr. Xavier Roy, Columbia University

Tue, 2019-04-09 00:00 - 01:00
Speaker: 
Dr. Xavier Roy
Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr. Murray

Title & Abstract: TBA

inquiries rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr. Milton Smith, MSU

Tue, 2018-12-04 12:00 - 13:00
Speaker: 
Dr. Milton Smith
Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr. Mindiola

Title & Abstract TBA

inquiries rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr. Katherine J. Franz, Duke

Tue, 2019-02-19 12:00 - 13:00
Speaker: 

Dr. Katherine Franz

Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr. Tomson/ Dmochowski

Title & Abstract TBA

inquires rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr. Michael Nippe, Texas A& M University

Tue, 2019-03-05 12:00 - 13:00
Speaker: 

Dr. Michael Nippe

Location: 

Carol Lynch lecture Hall

Chemistry Complex

Host: Dr. Tomson

Title & Abstract TBA

inquiries rvargas@sas.upenn.edu

Inorganic Chemistry Seminar: Dr.Linda Doerrer, Boston University

Tue, 2018-11-27 12:00 - 13:00
Speaker: 

Dr. Linda Doerrer

 

Title:  Teflon Coated Compounds and Their Chemistries

  Complexes surrounded by perfluorinated ligands have noticeably different physical and chemical properties than their non-fluorinated analogs.  Fluorinated ligands are well-known for their oxidative stability, and therefore make tempting targets for investigations in oxidative catalysis.  Our group has prepared a large family of first-row transition metal complexes of monodentate fluorinated alkoxide and aryoxide ligands, with the general form [M(ORF)n]m-.  These fluorinated ligands are the electronic equivalent of fluoride, based on spectrochemical studies and ligand field comparisons, but are quite distinct from [MFn]m- complexes in solubility, hydrolytic stability, and nuclearity.  More recently we have extended our investigations into bidentate systems, namely that of the perfluoropinacolate ligand.  This ligand endows its complexes with the same general characteristics as the monodentate systems investigated previously, with some additional new features as well.  In the [M(pinF)n]m- family, numerous members are air-stable and water soluble.  This talk will give an overview of our past work in homoleptic 3d metal complexes with monodentate perfluorinated ligands, and then move into published and unpublished work on perfluoropinacolate complexes.  Most recent highlights include some extraordinarily rare electronic structures, such as an S = 1 Co(III) complex, and unusual Sn(IV) and Sn(II) species. 
Location: 

Carol Lynch Lecture Hall

Chemistry Complex

Host: Dr.Schelter

inquiries rvargas@sas.upenn.edu

Department of Chemistry

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